Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on the Constituents of Luffa operculata COGN. I. : Isolation and Structures of Luperosides A-H, Dammarane-Type Triterpene Glycosides in the Herb
楠本 幸史長尾 常敦岡部 光山内 辰郎
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1989 年 37 巻 1 号 p. 18-22

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Eight dammarane-type triterpene glycosides named luperosides A-H were isolated from the dried herb of Luffa operculata COGN. (Cucurbitaceae). Their structures were determined on the basis of chemical and spectral evidence as follows. A : a 3, 20-bis-O-β-D-glucopyranoside of (20S)-dammar-24-ene-3β, 7β, 20-triol (Ag). B : a 20-O-β-gentiobioside of Ag. C : a 3-O-β-neohesperidoside-20-O-β-D-glucopyranoside of Ag. D : a 3-O-β-D-glucopyranoside-20-O-β-gentiobioside of Ag. E : a 3-O-β-neohesperidoside-20-O-β-D-xylopyranosyl-(1→6)-β-D-glucopyranoside of Ag. F : a 3-O-β-neohesperidoside-20-O-β-gentiobioside of Ag. G : a 3-O-β-neohesperidoside-20-O-β-gentiobioside of (20S)-dammar-23-ene-3β, 7β, 20, 25-tetraol. H : 3-O-β-neohesperidoside-20-O-β-gentiobiosides of (20S, 24S and R)-dammar-25-ene-3β, 7β, 20, 24-tetraols.
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