THE STEREOCHEMISTRY OF REDUCTIVE CARBOXYLATION PRODUCTS OF (1S, 8R)-1-METHYL-5, 6, 7, 8-TETRAHYDROINDAN-5-ONE

Motoo TORI; Masakazu SONO; Yoshinori ASAKAWA

doi:10.1248/cpb.37.534

Motoo TORI, Masakazu SONO, Yoshinori ASAKAWA

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Keywords: (1S, 8R)-1-Methyl-5, 6, 7, 8-tetrahydroindan-5-one, 1, 5-dimethyl-perhydroindan-4-one, Birch reduction, reductive carboxylation

JOURNAL FREE ACCESS

1989 Volume 37 Issue 2 Pages 534-535

DOI https://doi.org/10.1248/cpb.37.534

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Abstract

The title compound has been reductively carboxylated under the Birch reduction conditions. The resulting keto esters are assigned to cis and trans fused hydrindanones by transofrmations into 1, 5-dimethyl-4, 5, 6, 7, 8, 9-hexahydroindan-4-ones.

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