Mechanism of the Wolff Rearrangement

Minoru Tsuda; Setsuko Oikawa

doi:10.1248/cpb.37.573

著者情報

キーワード: Wolff rearrangement, reaction mechanism, oxirene, ketene, triplet state ketocarbone, 2-diazoethan-1-one, molecular orbital method, potential energy hypersurface

ジャーナルフリー

1989 年 37 巻 3 号 p. 573-575

DOI https://doi.org/10.1248/cpb.37.573

詳細

抄録

The direct formation of ketene occurs in a concerted fashion with the nitrogen loss reaction in the Wolff rearrangement of both cyclic and open-chain 2-diazoketones.The mechanism proposed the previous paper generalized to cover a wider range of experiments.No ketocarbone intermediate is produced in any case.

責任著者(Corresponding author)

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