Synthesis of Macrocyclic Terpenoids by Intramolecular Cyclization. XIV. Cyclization of 13, 14-Epoxygeranylgeranyl Phenyl Sulfide

Mitsuaki KODAMA; Kazuyoshi FUKUZUMI; Mitsushige KUMANO

doi:10.1248/cpb.37.1691

児玉三明, 福住和芳, 熊野充繁

著者情報

キーワード: α-sulfenyl carbanion, intramolecular cyclization, 13, 14-epoxygeranylgeranyl phenyl sulfide, 13-membered ring formation, sarcophytol A

ジャーナルフリー

1989 年 37 巻 7 号 p. 1691-1693

DOI https://doi.org/10.1248/cpb.37.1691

詳細

抄録

Cyclization of 13, 14-epoxygeranylgeranyl phenyl sulfide (2) was examined to determine whether 13- or 14-membered ring formation is preferred in the case of a disubstituted epoxide; the cis- and trans-epoxides were both found to cyclize to the 13-membered ring.

責任著者(Corresponding author)

J-STAGEへの登録はこちら（無料）