Novel Reactions of S, S'-Bis(1-phenyl-1H-tetrazol-5-yl) Dithiocarbonate

Kazuyoshi TAKEDA; Kanoko TSUBOYAMA; Hiroaki TAKAYANAGI; Rie SHIROKAMI; Masumi TAKEURA; Haruo OGURA

doi:10.1248/cpb.37.2334

Kazuyoshi TAKEDA, Kanoko TSUBOYAMA, Hiroaki TAKAYANAGI, Rie SHIROKAMI, Masumi TAKEURA, Haruo OGURA

Author information

Keywords: S, S'-(bis(1-phenyl-1H-tetrazol-5-yl)dithiocarbonate, X-ray crystal analysis amide, isothiocyanate, Friedel-Crafts reaction, carbonyl group insertion reaction

JOURNAL FREE ACCESS

1989 Volume 37 Issue 9 Pages 2334-2337

DOI https://doi.org/10.1248/cpb.37.2334

Details

Abstract

S, S'-Bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (1) was synthesized in good yield from 1-phenyl-5-mercapto-5H-tetrazole (2) and trichloromethyl chloroformate (TCF). THe structure of 1 was confirmed by using X-ray crystal analysis. The reagent (1) could be applied to the formatio of amides, Friedel-Crafts type reactions, isothiocyanate syntheses, and carbonyl group insertion reactions.

Corresponding author

Register with J-STAGE for free!