TOTAL SYNTHESIS OF (+)-MONOMORINE I VIA ASYMMETRIC α-KETONIC CLEAVAGE OF 8-AZABICYCLO[3.2.1]OCTAN-3-ONE

Takefumi MOMOSE; Naoki TOYOOKA; Sumie SEKI; Yoshiro HIRAI

doi:10.1248/cpb.38.2072

著者情報

キーワード: (+)-monomorine I, asymmetric α-ketonic cleavage, 'fork head' ketone, asymmetric deprotonation, 8-azabicyclo[3.2.1]octan-3-one, σ-symmetric bicycic ketone, ant pheromone, σ-symmetric pyrrolidine, ozonolysis

ジャーナルフリー

1990 年 38 巻 7 号 p. 2072-2074

DOI https://doi.org/10.1248/cpb.38.2072

詳細

抄録

The total synthesis of (+)-monomorine I and preparation of cis-2, 5-difunctionalized pyrrolidines, as a chiral synthon, starting with asymmetric cleavage of the 'fork head' ketone of 8-azabicyclo[3.2.1]octan-3-one are described.

責任著者(Corresponding author)

J-STAGEへの登録はこちら（無料）