A Synthesis of (-)-Bursatellin

Katsumi KAWAMINE; Rie TAKEUCHI; Masaaki MIYASHITA; Hiroshi IRIE; Keiko SHIMAMOTO; Yasufumi OHFUNE

doi:10.1248/cpb.39.3170

Katsumi KAWAMINE, Rie TAKEUCHI, Masaaki MIYASHITA, Hiroshi IRIE, Keiko SHIMAMOTO, Yasufumi OHFUNE

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Keywords: (-)-bursatellin, sea hare, N-Boc-tyrosine, potassium persulfate, oxidation, formylation, cyanation

JOURNAL FREE ACCESS

1991 Volume 39 Issue 12 Pages 3170-3171

DOI https://doi.org/10.1248/cpb.39.3170

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Abstract

A synthesis of (-)-bursatellin has been accomplished by an application of a new procedure for oxidation at a benzylic position with K₂S₂O₈ to 1-acetoxy-2(S)-N-Boc-amino-3-(4-benzyloxyphenyl)propane as a key step.

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