Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on as-Triazine Derivatives. XVI. Reaction of 1, 2, 4-Triazinecarbonitriles with Carbanions
Setsuya OHBA, Shoetsu KONNO, Hiroshi YAMANAKA
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Keywords: active methylene compound, addition, carbanion, cyano group, Grignard reagent, ketone, substitution, 1, 2, 4-triazine
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1991 Volume 39 Issue 2 Pages 486-488

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Abstract
A cyano group in 1, 2, 4-triaznes, regardless of its position, acted as an effective leaving group in reactions with carbanions. Thus, the reactions gave the corresponding substituted products in place of the compounds formed by addition reaction of carbanions to the cyano group. Grignard reaction of these carbonitriles is also described.
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© The Pharmaceutical Society of Japan
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