MEISENHEIMER REARRANGEMENT OF 2-ETHENYL-1, 4, 5, 10b-TETRAHYDRO-2H-AZETOPYRIDO[3, 4-b__-]INDOLE N-OXIDES : NEW ROUTE TO THE 12(S)CARBA-EUDISTOMIN SKELETON

Takushi KURIHARA; Miki DOI; Kayo HAMAURA; Hirofumi OHISHI; Shinya HARUSAWA; Ryuji YONEDA

doi:10.1248/cpb.39.811

栗原拓史, 土井美紀, 濱浦香代, 大石宏文, 春沢信哉, 米田龍司

著者情報

キーワード: 3, 4-dihydro-β-carboline, tetrahydroazetopyridoindole, tetrahydropyridooxazepine, tetrahydropyridoisoxazole, Meisenheimer rearrangement, m-chloroperbenzoic acid, carbaeudistomin, X-ray analysis

ジャーナルフリー

1991 年 39 巻 3 号 p. 811-813

DOI https://doi.org/10.1248/cpb.39.811

詳細

抄録

Oxidation of 1, 2-cis- and 1, 2-trans-2-ethenyl-1, 4, 5, 10b-tetrahydro-2H-azetopyrido[3, 4-b__-]indoles 4 and 5 with m_--chloroperbenzoic acid (mCPBA) geve tetrahydropyridooxazepine 7, which has a 12(S)carba-eudistomin skeleton, and tetrahydropyridoisoxazole 8 by Meisenheimer rearrangement.

責任著者(Corresponding author)

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