A Stereoselective Synthesis of (±)-Pestalotin
1991 年 39 巻 7 号 p. 1866-1868
詳細
1991 年 39 巻 7 号 p. 1866-1868
(±)-Pestalotin (1) was synthesized by employing a stereoselective reduction of a 5-alkyltetronate derivative (3) and a two-carbon elongation reaction of the aldehyde (13) with ethyl diazoacetate in the presence of stannous chloride as key steps.
