Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Substituent Effect on the Benzyl Groups in Sommelet-Hauser Rearrangement
Tetsuya TANAKA, Naohiro SHIRAI, Yoshiro SATO
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Keywords: ylide, Sommelet-Hauser rearrangement, desilylation, fluoride, sigmatropic rearrangement, substituent effect
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1992 Volume 40 Issue 2 Pages 518-520

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Abstract
The effects of substituents (MeO, Me, H, Br, CN, NO2) of the benzyl groups in the Sommelet-Hauser rearrangement of N, N-bis(substituted benzyl)-N-methyl(trimethylsilyl)methylammonium halides with cesium fluoride in N, N-dimethylformamide were examined.
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© The Pharmaceutical Society of Japan
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