Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
A NOVEL TRIMETHYLSILYL GROUP MIGRATION : FORMATION OF ETHYL 5-CHLORO-4-TRIMETHYLSILYL-2-FUROATE WITH SULFURYL CHLORIDE IN DICHLOROMETHANE
Kouji NAKAYAMA, Akira TANAKA
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Keywords: ethyl 5-trimethylsilyl-2-furoate, ethyl 5-chloro-4-trimethylsilyl-2-furoate, sulfuryl chloride, trimethylsilyl migration, halodesilylation, chlorodesilylation
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1992 Volume 40 Issue 7 Pages 1966-1968

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Abstract
The reaction of ethyl 5-trimethylsilyl-2-furoate (1) with sulfuryl chloride in dichloromethane afforded an unexpected product, ethyl 5-chloro-4-trimethylsilyl-2-furoate (2a), through a novel trimethylsilyl group migration.
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© The Pharmaceutical Society of Japan
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