1993 年 41 巻 5 号 p. 919-922
Chelating glass beads (SAB) containing salicylideneamino-2-thiophenol (SATP) as a functional group were synthesized for the selective adsorption and separation of ionic aluminum (Al3+). SAB was prepared by reacting amino-propyl-CPG (controlled pore glass) with SATP, shielded from light in toluene at 110°C for 12 h. The exchange capacity of SAB for Al3+ was about 1.1 mmol/g (support). When SAB was packed into a column, only Al3+ was retained out of all the metal ions examined, at pH 5.5 with hydroxylamine hydrochloride present. Aluminum ion was then eluted quantitatively with nitric acid. Aluminum samples below 1 ppm were concentrated by a factor of 100. This column method applied to the preconcentration of Al3+ in drinking water.