Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Asymmetric Heck-Type Reaction Utilizing Hypervalent Alkenyliodonium Salt
Yuji KURIHARA, Mikiko SODEOKA, Masakatsu SHIBASAKI
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Keywords: asymmetric Heck-type reaction, hypervalent iodonium salt, palladium, catalysis, asymmetric C-C bond formation
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1994 Volume 42 Issue 11 Pages 2357-2359

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Abstract
Asymmetric Heck-type reaction of 1-cyclohexenylphenyliodonium salt with 2, 3-dihydrofuran was investigated for the first time. The optically active (up to 78% ee) coupling product was obtained in low to moderate yield. The potential and associated problems of this asymmetric reaction are discussed.
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© The Pharmaceutical Society of Japan
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