Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Photo-Oxidation of 2-Methylamino-3-(1-piperidinylmethyl)-1, 4-naphthoquinone
太田 俊作日向 靖成川崎 郁勇山下 正行
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1994 年 42 巻 11 号 p. 2360-2362

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2-Methylamino-3-(1-piperidinylmethyl)-1, 4-naphthoquinone (7) was prepared via several steps from 2-methyl-1, 4-naphthoquinone (vitamin K3, 3). The quinone (7) was photochemically oxidized to 2-methylamino-3-(1-piperidinylcarbonyl)-1, 4-naphthoquinone (8) and/or 2-alkoxycarbonyl-3-methylamino-1, 4-naphthoquinone (9), depending on the solvent used.
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