Absolute Structure of 2'-Desacetoxyaustrospicatine Established by X-Ray analysis and Circular Dichroism Spectroscopy

Yaeko KONDA; Tomomitsu SASAKI; Xue-Long SUN; Xian LI; Masayuki ONDA; Hiroaki TAKAYANAGI; Yoshihiro HARIGAYA

doi:10.1248/cpb.42.2621

根田八重子, 佐々木智満, 孫学龍, / 恩田政行, 高柳弘明, 針谷義弘, Yoshihiro HARIGAYA

著者情報

キーワード: 2'-desacetoxyaustrospicatin, absolute structure, X-ray analysis, CD spectruym, taxane diterpene

ジャーナルフリー

1994 年 42 巻 12 号 p. 2621-2624

DOI https://doi.org/10.1248/cpb.42.2621

詳細

抄録

Three taxane diterpenes, taxinine (1), taxinine B (2), and 2'-desacetoxyaustrospicatin (3), have been isolated from Taxus cuspidata SIEB et ZUCC. The absolute stereostructure of 3 has been determined by a combination of X-ray analysis and circular dichroism (CD) spectroscopy. Complete assignments of ¹H- and ¹³C-nuclear magnetic resonance (NMR) signals for 1 and 2 have been made on the basis of two-dimensional (2D) NMR techniques.

責任著者(Corresponding author)

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