Convenient Synthesis of the Epoxy Fragment of Azinomycin B

Yaeko KONDA; Tomomi MACHIDA; Tomomitsu SASAKI; Kazuyoshi TAKEDA; Hiroaki TAKAYANAGI; Yoshihiro HARIGAYA

doi:10.1248/cpb.42.285

Yaeko KONDA, Tomomi MACHIDA, Tomomitsu SASAKI, Kazuyoshi TAKEDA, Hiroaki TAKAYANAGI, Yoshihiro HARIGAYA

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Keywords: azinomycin B, Sharpless asymmetric epoxidation, allylic alcohol, asymmetric synthesis, epoxide, X-ray

JOURNAL FREE ACCESS

1994 Volume 42 Issue 2 Pages 285-288

DOI https://doi.org/10.1248/cpb.42.285

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Abstract

A new convenient route for asymmetric synthesis of the epoxy fragment of azinomycin B by Sharpless asymmetric epoxidation of secondary allylic alcohol is described.

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