Synthetic Studies on Aromadendrane-Type Compounds. I. Stereoselective Construction of Aromadendrane- and Alloaromadendrane-Type Skeletons

Tetsuaki TANAKA; Yousuke FUNAKOSHI; Kenji UENAKA; Kimiya MAEDA; Hidenori MIKAMIYAMA; Yoshiji TAKEMOTO; Naoyoshi MAEZAKI; Chuzo IWATA

doi:10.1248/cpb.42.300

田中徹明, 船越洋祐, 上中健司, 前田公也, 三神山秀勲, 竹本佳司, 前崎直容, 岩田宙造

著者情報

キーワード: aromadendrane, alloaromadendrane, stereoselective reduction, aldol condensation, tricyclo[6.3.0.0^{2, 4}]undecane, (+)-3-carene

ジャーナルフリー

1994 年 42 巻 2 号 p. 300-305

DOI https://doi.org/10.1248/cpb.42.300

詳細

抄録

As a preliminary study for the synthesis of aromadendrane- and alloaromadendrane-type compounds, trans and cis B/C-ring compounds (18 and 22) were synthesized from (+)-(1S, 2R, 4R, 7R)-3, 3, 7-trimethyltricyclo[6.3.0.0^{2, 4}]undec-8-en-10-one (3) as a common intermediate, which was obtained from (+)-3-carene via an intramolecular aldol condensation as a crucial step.

責任著者(Corresponding author)

J-STAGEへの登録はこちら（無料）