BIOMIMETIC SYNTHESIS OF NAUCLEA INDOLE ALKALOIDS, NAUCLEIDINAL, AND 3-EPI-NAUCLEIDINAL, BY STEREOSELECTIVE REARRANGEMENT OF STRICTOSAMIDE AND THE VINCOSIDE LACTAM AGLYCONES

Hiromitsu TAKAYAMA; Yuhko MIYABE; Toshiaki SHITO; Mariko KITAJIMA; Norio AIMI

doi:10.1248/cpb.44.2192

Hiromitsu TAKAYAMA, Yuhko MIYABE, Toshiaki SHITO, Mariko KITAJIMA, Norio AIMI

著者情報

キーワード: biomimetic synthesis, Nauclea alkaloid, naucleidinal, 3-epi-naucleidinal, strictosamide, vincoside lactam

ジャーナルフリー

1996 年 44 巻 11 号 p. 2192-2194

DOI https://doi.org/10.1248/cpb.44.2192

詳細

抄録

Based on a biogenetic consideration, a Nauclea alkaloid, naucleidinal (6), and its 3-epimer (7) were stereoselectively prepared from the aglycones of strictosamide and the vincoside lactam, and their absolute stereochemistry was confirmed.

責任著者(Corresponding author)

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