Asymmetric Induction Reactions. VII. Palladium-Catalyzed Asymmetric α-Allylations of Carbonyl Compounds Using Chiral Sulfonamides as Chiral Ligands

Kunio HIROI; Akira HIDAKA; Rie SEZAKI; Yumiko IMAMURA

doi:10.1248/cpb.45.769

Kunio HIROI, Akira HIDAKA, Rie SEZAKI, Yumiko IMAMURA

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Keywords: asymmetric allylation, palladium catalyst, chiral sulfonamide, chiral ligand, catalytic asymmetric synthesis

JOURNAL FREE ACCESS

1997 Volume 45 Issue 5 Pages 769-777

DOI https://doi.org/10.1248/cpb.45.769

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Abstract

Palladium-catalyzed asymmetric α-allylations of carbonyl compounds were studied using various kinds of chiral sulfonamides derived from optically active α-amino acids as chiral ligands. Participation of the sulfonamide functionality in the palladium catalysis is discussed.

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