REDUCTION OF DITHIOACETALS WITH SmI2 IN BENZENE-HMPA

Munetaka KUNISHIMA; Daisuke NAKATA; Kazuhito HIOKI; Shohei TANI

doi:10.1248/cpb.46.187

REDUCTION OF DITHIOACETALS WITH SmI₂ IN BENZENE-HMPA

Munetaka KUNISHIMA, Daisuke NAKATA, Kazuhito HIOKI, Shohei TANI

著者情報

キーワード: samarium iodide, dithioacetals, sulfides, reduction

ジャーナルフリー

1998 年 46 巻 1 号 p. 187-189

DOI https://doi.org/10.1248/cpb.46.187

詳細

抄録

Partial reduction of dithioacetals to the corresponding sulfides was effected by samarium iodide in the presence of either t-BuOH or acetic acid in benzene-HMPA. An α-sulfenyl anion was shown to be involved.

責任著者(Corresponding author)

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