Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Cycloarta-16, 24-dien-3β-ol : Revised Structure of Cimicifugenol, a Cycloartane Triterpenoid
Toshihiro AKIHISARyuichi HIDESHIMAKazuo KOIKEYumiko KIMURATamotsu NIKAIDO
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1999 年 47 巻 8 号 p. 1157-1160

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The structure of a triterpene alcohol isolated from the nonsaponifiable lipids of both the root and aerial part extracts of Cimicifuga simplex (Ranunculaceae) was established to be cycloarta-16, 24-dien-3β-ol (1). Spectral identity of the 24, 25-dihydro derivative (4) of 1 with 24, 25-dihydrocimicifugenol demonstrated that cimicifugenol, previously assigned the erroneous structure of cycloarta-7, 24-dien-3β-ol, possesses structure 1.

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