Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Reactivity of an o-Indoloquinone to 1-and 2-Azadienes
Vania BERNARDES GENISSONPascal NEBOIS
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2000 Volume 48 Issue 6 Pages 893-894

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Abstract
The cycloaddition reactions of o-indoloquinone 4 to azadienes are described. With 1-azadiene 2, quinone 4 works as a dienophile to give the directly aromatized cycloadduct 6. In contrast, when 2-azadiene 3 is used, the cycloaddition occurs with CO-4, indicating that this system functions as a heterodienophile.
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© The Pharmaceutical Society of Japan
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