Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
A Novel Agarofuran Sesquiterpene, Celahin D from Celastrus hindsii BENTH.
Hui-Chi HUANGChien-Chang SHENChieh-Fu CHENYang-Chang WUYao-Haur KUO
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2000 年 48 巻 7 号 p. 1079-1080

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A novel agarofuran sesquiterpene polyol ester, 1β, 2β, 6α, 15β-tetracetoxy-8β, 9α-dibenzoyloxy-β-dihydroagarofuran (celahin D) (1), two known analogues of 1, 1β-acetoxy-8β, 9α-dibenzoyloxy-4α, 6α-dihydroxy-2β(α-methylbutanoyloxy)-β-dihydroagarofuran (2) and 1β-acetoxy-8β, 9α-dibenzoyloxy-6α-hydroxy-2β(α-methylbutanoyloxy)-β-dihydroagarofuran (3), and a known cytotoxic sesquiterpene pyridine alkaloid, emarginatine E (4) were isolated from the stems of Celastrus hindsii BENTH. Three known triterpenes, loranthol (5), lupenone (6) and friendelinol (7) were also obtained from the titled plant. Structural elucidation of compound 1 was established by 2D NMR spectra.

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