Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on the Sulfur-containing Chelating Agents. II. Syntheses of β-Mercaptoketones and their Copper Chelates. (2).
Hisashi TanakaAkira Yokoyama
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1960 Volume 8 Issue 4 Pages 280-283

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Abstract
β-Mercaptoketones, β-mercapto-β-(m-tolyl)-and β-mercapto-β-(p-chlorophenyl)-propiophenone, β-mercapto-β-phenyl-p-chloropropiophenone, β-mercapto-β-phenyl-p-methoxypropiophenone, and β-mercapto-β-(1-naphthyl)propiophenone, were prepared by the addition of hydrogen sulfide to the corresponding α-benzylideneacetophenones and α-1-naphthylideneacetophenone. These mercaptoketones formed chelate compounds with copper and the ratio of ligand to copper was found to be 1 : 1.
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© The Pharmaceutical Society of Japan
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