Chiroptical Properties of Nonanuclear Tb(III) Clusters with Chiral Champhor Derivative Ligands

Satoshi Wada; Yuichi Kitagawa; Takayuki Nakanishi; Koji Fushimi; Yasuchika Hasegawa

doi:10.1380/ejssnt.2015.31

Conference -CIF'15-

Chiroptical Properties of Nonanuclear Tb(III) Clusters with Chiral Champhor Derivative Ligands

Satoshi Wada, Yuichi Kitagawa, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa

著者情報

キーワード: Lanthanides, Photoluminescence, Chirality, Circularly polarized luminecnece, Visible/ultraviolet absorption spectroscopy

ジャーナルフリー

2015 年 13 巻 p. 31-34

DOI https://doi.org/10.1380/ejssnt.2015.31

詳細

抄録

The chiroptical properties of nonanuclear Tb(III) clusters are reported. The nonanuclear Tb(III) clusters are composed of nine Tb(III) ions, ten μ-OH parts, and sixteen chiral organic ligands, (±)-bornyl salicylate. Their chiroptical properties were estimated by circular dichroism (CD) and circularly polarized luminescence (CPL). Their electronic structures were calculated using TD-DFT (B3LYP/6-31G(d)) method. [DOI: 10.1380/ejssnt.2015.31]

責任著者(Corresponding author)

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