1B07 ゲル化能を有するトロポノイド液晶分子の合成と性質(化学・材料)

抄録

New troponoid liquid crystals (1T-6T) with a bitropone core were prepared. The ester derivatives (3T) had enantiotropic smectic A and C phases and the amide (4T) had nematic and smectic C phases, while troponoid hexacatenar compounds (5T, 6T) had an enantiotropic columnar phase. The amide derivatives (6T) had gelling properties for organic solvents such as ethyl acetate, hexadecane, and 1-decanol.