繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
一般報文
Graft Polymerization of Cyclic Compounds on Cellulose Dissolved in Tetrabutylammonium Fluoride ⁄ Dimethyl Sulfoxide
Isao IkedaKiyotaka WashinoYasushi Maeda
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2003 年 59 巻 3 号 p. 110-114

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抄録
Cyclic compounds such as lactones and N-carboxy α-amino acid anhydrides (NCAs) were graft-polymerized on cellulose dissolved in tetrabutylammonium fluoride ⁄ dimethyl sulfoxide (TBAF ⁄ DMSO). ε-Caprolactone was grafted on cellulose with grafting of 64% in this solvent system. NCAs were also grafted with grafting of over 100%. It is thought that an increase in the nucleophilicity of hydroxyl groups of cellulose by the interaction with TBAF was related to this polymerization.
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© 2003 The Society of Fiber Science and Technology, Japan
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