繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
ジメチルスルホキシド・ホルムアルデヒド系溶解セルロースのブチルエステル化反応
荒井 健一郎荻原 允隆
著者情報
ジャーナル フリー

1980 年 36 巻 2 号 p. T82-T84

詳細
抄録
Bleached sulfite pulp was dissolved with formaldehyde in dimethyl sulfoxide, and homogeneous butyration of the cellulose by n-butyric anhydride in the presence of pyridine was examined. Cellulose butyrates with a degree of substitution up to 1.8 were obtained in recovery yield ca. 90%, and were found to be more soluble in various organic solvents than the cellulose acetates with a degree of substitution of 2.0-2.4, prepared with a similar method. The cellulose butyrate film prepared from its acetone solution was colorless and transparent, and not so hard as the cellulose acetate film, and had rather lower tensile strength. The infrared spectrum of the cellulose butyrate was also investigated.
著者関連情報
© (社)繊維学会
前の記事 次の記事
feedback
Top