電気学会論文誌A(基礎・材料・共通部門誌)
Online ISSN : 1347-5533
Print ISSN : 0385-4205
ISSN-L : 0385-4205
特集解説論文
中性子回折と放射光によるLa-Co置換フェライトの局所構造解析
小林 義徳
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ジャーナル フリー

2016 年 136 巻 8 号 p. 472-477

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The La-Co substituted magnetoplumbite type (M-type) hexagonal ferrites are known to have the higher magnetic crystalline anisotropy compared with conventional M-type Sr ferrites. The site occupation of cation in the crystal structure has been analyzed by neutron diffraction and EXAFS (Extended X-ray Absorption Fine Structure) spectroscopy in order to clarify the correlation between the local structural change and the improvement of the magnetic anisotropy. The EXAFS analysis has suggested that Co ions were located in the 4f1, which showed good agreement with the results by neutron diffraction and XMCD analysis.
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