JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
PREDICTION OF SOLVENT SELECTIVITY IN EXTRACTIVE DISTILLATION AND OF VAPOR-LIQUID EQUILIBRIA OF HYDROCARBONS
YASUHIKO ARAISHOZABURO SAITOSIRO MAEDA
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1969 年 2 巻 1 号 p. 8-13

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The Scatchard-Hildebrand theory of regular solutions was modified by introducing the excess entropy of mixing term and by using temperature dependent solubility parameters. A comparison was made of the present treatment with the data available in the literature and the experimental results concerning the n-hexane-benzene-toluene and n-hexane-benzene-monochlorobenzene systems. The modified theory was shown, from the knowledge of pure components only, to be capable of predicting vapor -liquid equilibria for systems not containing polar components and useful for screening solvents effective for extractive distillation.
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© The Society of Chemical Engineers, Japan
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