Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
結晶化ガラスA-Wと擬似体液中でその表面に形成されたアパタイト層の透過電子顕微鏡観察
大槻 主税青木 幸生小久保 正板東 義雄根尾 昌志中村 孝志
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1995 年 103 巻 1197 号 p. 449-454

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In the interior of glass-ceramic A-W, both the apatite and β-wollastonite were homogeneously dispersed in a glassy matrix, taking a form of rice grain 50 nm in width and 100 nm in length. The apatite layer formed on the glass-ceramic in the simulated body fluid consisted of fine needle-like apatite crystals about 10 nm in thickness and 100 nm in length, which are elongated along c-axis and randomly oriented. The apatite crystals in the surface layer were in direct contact with those within the glassceramic without intervention of such silica gel layer as observed for Bioglass®-type glasses. No crystallographic relation was observed between them. The apatite crystals in the surface layer were calciumdeficient, and contained small amounts of Mg and Si.
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