The effect of Au addition on crystallization was investigated for TeOx-Au films used for optical recording materials. Crystallization phases precipitated from the films were found to be AuTe2 in low Au content films and AuTe1.7 in high Au content films. The crystallization rate was much faster in the case of crystalline AuTe1.7 than in the case of crystalline AuTe2. The time required for the signal saturation due to the crystallization of the films irradiated by laser (850nm in wavelength, 8mW/um2 in power) was shortened up to 60ms for the films in which AuTe1.7 was precipitated from 30s for the pure TeOx films in which crystalline Te was precipitated. The transformation mechanism from the amorphous to the crystalline state in these films is discussed.