The oxidation of TiB2 added with Cr and C prepared by pressureless sintering at 1900°C was investigated TiB2 containing Cr and C was heated at 800°C to 1100°C for 36h in air, and weight change was measured to estimate the oxidation resistance. The TiB2 showed a good oxidation resistance at 800°C because of the surface film of TiO2 (rutile) and B2O3 formed by oxidation, which formed a barrier as an oxidation resistant layer. The weight gain of a TiB2 specimen at 800°C for 36h in air was about 1.8mg/cm2, that of the Cr and C containing specimen was about 27mg/cm2 at 1100°C for 36h.