材料と環境
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
イットリア粒子分散強化合金の高温腐食と高温酸化
冨塚 功小泉 裕中沢 静夫沼田 英夫大野 勝美宮崎 昭光
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1993 年 42 巻 8 号 p. 514-520

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Addition of yttrium to nickel-base alloys is known to improve their oxidation resistance. It is not clear, however, if a comparable effect is expected by addition of yttria or not. This question was investigated by comparing a hot corrosion behavior in a crucible and cyclic oxidation behavior in oxygen gas of a yttria added alloy with those of its yttria-free control of the same composition. As for the hot-corrosion, addition of yttria caused no significant difference for the solution-treated specimens, while it increased corrosion susceptibility for the as-extruded ones. The increase was considered to be due to a smaller crystal-grain size for the yttria-added specimen. Addition of yttria increased corrosion susceptibility to the dry oxidation as well. The reason was less clear. A possible one was a fine scale structure caused by yttria addition, which might have prevented formation of protective alumina layer over the alloy surface.
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