材料と環境
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
腐食に及ぼす光の作用と紫外光による不働態皮膜改質
藤本 慎司
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ジャーナル フリー

2002 年 51 巻 10 号 p. 453-457

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Modification of passive film by photo irradiation is described as a photo quantum process in the semiconductor thin film. Ultraviolet light irradiation accelerates Cr enrichment in the passive film of Fe-Cr and Type 304 stainless steel, resulting in improved corrosion resistance. The process observed in neutral and acid solution is described in terms of structure change in the passive film induced by photo excitation. Some quantum effects caused by photo excitation are discussed, and possible mechanisms for such photo protection are proposed.
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