O209 超臨界水中反応の反応熱測定装置の開発(セッション4:技術～基礎～,口頭発表)

抄録

Determination of heat of reaction for chemical reactions taking place in supercritical water is important for process engineering, but no measurement has been reported so far. The purpose of this study is to establish the method to determine the heat of reaction in supercritical water. Glucose was decomposed in supercritical water using a tubular reactor, and inlet and outlet temperatures were measured that allowed the determination of the heat of reaction. The conditions were a temperature of 400,450℃ and pressure of 23.5MPa and glucose concentration of 0.05M.