O-208 グリセリンの水素化分解反応による1, 3-プロパンジオールの製造(セッション4:技術-マテリアル変換-,口頭発表)

抄録

Glycerol hydrogenolysis was catalyzed by Pt/WO_3/ZrO_2 to give 1,3-propanediol (1,3-PD) in the yields up to 24 %. The catalytic activities and the selectivity toward 1,3-PD were remarkably affected by the type of support, loaded noble metal (NM) and the preparation/impregnation procedure. Controlled experiments show that the active site of catalyst for the formation of 1,3-PD may be the Pt over WO_3 supported on ZrO_2.