純NiおよびNi-Cr合金における水素脆化挙動の結晶粒径依存性

抄録

The grain size effects on the hydrogen embrittlement susceptibility of pure Ni and Ni-20Cr alloy were investigated. The hydrogen embrittlement susceptibility was evaluated by tensile testing under electrochemical hydrogen charging. Relative elongation, defined as the elongation under hydrogen charging divided by elongation in air, increased with increasing grain size in pure Ni (the grain size was in the range of 11-22 µm). In contrast, the relative elongation of Ni-20Cr alloy increased with decreasing grain size from 13 to 1.8 µm. Correspondingly, intergranular fracture was suppressed by grain coarsening in pure Ni and grain refinement in the Ni-20Cr alloy. In addition, the intergranular fracture surface in pure Ni showed curved slip lines, and in the Ni-20Cr alloy showed straight line marks. These fractographic features imply that the mechanisms of the hydrogen-assisted intergranular crack growth were different in pure Ni and Ni-20Cr alloy and this can be attributed to the difference in stacking fault energy.