The solubility of hydrogen in pure liquid iron has been measured as a function of pressure and temperature by the sampling method. Sieverts law is obeyed at all pressure up to one atomosphre. The logarithms of K(=H⁄\sqrtPH) and the standard free energy of solution of hydrogen in pure liquid iron may be expressed as:
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The solubility is reduced by carbon and the effect of carbon on the activity coefficient of hydrogen has been determined as follows:
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