Novel Synthetic Route to 2,5-Disubstituted Furan Derivatives through Surface Active Agent-Catalysed Dehydration of D(-)-Fructose

Kazuhiko HAMADA; Hiroshi YOSHIHARA; Gohfu SUZUKAMO

doi:10.5650/jos.50.533

Journal of Oleo Science

Online ISSN : 1347-3352
Print ISSN : 1345-8957
ISSN-L : 1345-8957

Notes

Novel Synthetic Route to 2,5-Disubstituted Furan Derivatives through Surface Active Agent-Catalysed Dehydration of D(-)-Fructose

Kazuhiko HAMADA, Hiroshi YOSHIHARA, Gohfu SUZUKAMO

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Keywords: D(-)-fructose, surface active agent, 5-methyl-2-furfural, 2,5-dimethyl furan, 5-chloromethyl-2-furfural, magnesium halide

JOURNAL FREE ACCESS

2001 Volume 50 Issue 6 Pages 533-536

DOI https://doi.org/10.5650/jos.50.533

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Abstract

5-Chloromethyl-2-furfural, generated in situ by surface active agent-catalysed dehydration of D(-)-fructose, was conducted to obtain 5-methyl-2-furfural,2,5-dimethyl furan,2,5-hexanedione and 2,5-dimethyl-1-thioureidopyrrole.

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