Solution Properties of Sulfate-Type Fluoro-Hybrid Anionic Surfactants with a Benzene Ring in Their Molecules

Chengxu SUN; Haruhiko MIYAZAWA; Yukishige KONDO; Norio YOSHINO; Koki ABE; Masanobu SAGISAKA; Boonyarach KITIYANAN; Takahiro OHKUBO; Hideki SAKAI; Masahiko ABE

doi:10.5650/jos.53.371

Detergents and Interface Science

Solution Properties of Sulfate-Type Fluoro-Hybrid Anionic Surfactants with a Benzene Ring in Their Molecules

Chengxu SUN, Haruhiko MIYAZAWA, Yukishige KONDO, Norio YOSHINO, Koki ABE, Masanobu SAGISAKA, Boonyarach KITIYANAN, Takahiro OHKUBO, Hideki SAKAI, Masahiko ABE

Author information

Chengxu SUN
Department of Pure and Applied Chemistry, Graduate School of Science and Technology, Tokyo University of Science
Haruhiko MIYAZAWA
Department of Industrial Chemistry, Graduate School of Engineering, Tokyo University of Science
Yukishige KONDO
Department of Industrial Chemistry, Graduate School of Engineering, Tokyo University of Science
Institute of Colloid and Interface Science, Tokyo University of Science
Norio YOSHINO
Department of Industrial Chemistry, Graduate School of Engineering, Tokyo University of Science
Institute of Colloid and Interface Science, Tokyo University of Science
Koki ABE
School of Chemical Engineering and Material Science, University of Oklahoma
Masanobu SAGISAKA
Department of Pure and Applied Chemistry, Graduate School of Science and Technology, Tokyo University of Science
Boonyarach KITIYANAN
The Petroleum and Petrochemical College, Chulalongkorn University
Takahiro OHKUBO
Institute of Colloid and Interface Science, Tokyo University of Science
Hideki SAKAI
Department of Pure and Applied Chemistry, Graduate School of Science and Technology, Tokyo University of Science
Institute of Colloid and Interface Science, Tokyo University of Science
Masahiko ABE
Department of Pure and Applied Chemistry, Graduate School of Science and Technology, Tokyo University of Science
Institute of Colloid and Interface Science, Tokyo University of Science

Keywords: fluoro-hybrid surfactant, aggregation number, vesicle, diffusion coefficient, sulfate

JOURNAL FREE ACCESS

2004 Volume 53 Issue 8 Pages 371-376

DOI https://doi.org/10.5650/jos.53.371

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Abstract

Two novel sulfate-type fluoro-hybrid anionic surfactants with a bezene ring in their molecules, F8H3OS and F6H5OS, were synthesized and their solution properties were investigated. Both of the hybrid surfactants were found to show an outstanding surface and interfacial tension lowering ability. F8H3OS formed compact micelles with small aggregation numbers and the micelles coagulated with increase in the surfactant concentration, while F6H5OS formed micelles at its low concentration and the micelles were transformed into vesicles at high concentrations of the surfactant.

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