Journal of Oleo Science
Online ISSN : 1347-3352
Print ISSN : 1345-8957
ISSN-L : 1345-8957
Biochemistry and Biotechnology
Synthesis and Physiological Activity of Ureas and Amides with Carvone Residues
Shinya TachibanaYoshihumi MaegawaMasato Nomura
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2007 Volume 56 Issue 6 Pages 303-307

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Abstract
The synthesis and herbicidal activity of ureas and amides with carvone residues were examined. (S)-(+)-(1) and (R)-(-)-Carvone(2) were converted to the respectively, primary amines(3) and (4) by oximation and reduction with LiAlH4. Primary amine derivatives were further converted into the urea and amide compounds (3a)∼(3e) and (4a)∼(4e). The herbicidal activity of products (3a)∼(3e) and (4a)∼(4e) towards weeds found in a paddy field and field was measured in the pot. Products (3a) showed a particularly strong inhibitory effect on the growth of Amaranthus retroflexus(AR) and Setaria viridis(SV).
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© 2007 by Japan Oil Chemists' Society
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