Journal of Oleo Science
Online ISSN : 1347-3352
Print ISSN : 1345-8957
ISSN-L : 1345-8957
Chemistry and Organic Synthesis
Synthesis and Characterization of an Organic Reagent 4-(6-Bromo-2-Benzothiazolylazo) Pyrogallol and Its Analytical Application
N. A. NaserK. H. KahdimD. N. Taha
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JOURNAL FREE ACCESS

2012 Volume 61 Issue 7 Pages 387-392

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Abstract
Organic reagent, 4-(6-Bromo-2-Benzothiazolylazo) pyrogallol (4-Br-BTAP), was synthesized by coupling reaction of diazotized 2-amino-6-bromobenzothiazole with pyrogallol and purified using ethanol recrystallization method. Analysis and characterization of synthesized product were carried out using melting point, elementary analysis, IR and H1-NMR. Dissociation constants of the organic reagent were calculated by spectrophotometric method. Absorption spectra of the 4-Br-BTAP in solvents of different polarities were investigated. Analytical application of 4-Br-BTAP was established with Cu (II) and Pd (II).
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© 2012 by Japan Oil Chemists' Society
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