Journal of Oleo Science
Online ISSN : 1347-3352
Print ISSN : 1345-8957
ISSN-L : 1345-8957
General Subjects
Nanoarchitectonics for Improving Catalytic Performance of α-Alumina-supported Gold Nanoflower by Water Extraction and Ultraviolet–Ozone Treatment
Yoshiro ImuraHaruna SaitoYuta JinoRyota AkiyamaClara Morita-ImuraTakeshi Kawai
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JOURNAL OPEN ACCESS

2024 Volume 73 Issue 9 Pages 1241-1247

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Abstract

Shape-controlled nanocrystals, such as nanoflowers, are expected to serve as innovative nanocatalysts with high catalytic activity. It is well-established that these nanocrystals can be readily synthesized with specific shapes using colloidal methods in solutions containing capping agents. However, these capping agents tend to reduce the catalytic activity of nanocatalysts. Therefore, it is imperative to remove these agents without altering the morphology to enhance catalytic efficiency. In this study, we developed a method for eliminating melamine, a common capping agent, from supported Au nanoflowers using water extraction and ultraviolet-ozone treatment. This process significantly enhances the catalytic performance, particularly for alcohol oxidation reactions such as the conversion of 1-phenylethyl alcohol to acetophenone.

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© 2024 by Japan Oil Chemists' Society

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