Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Temperature Dependence of the Nuclear Quadrupole Relaxation Rate in Silver and Sodium Halide Crystals
Toshihiro YamanishiTatsuo KanashiroYoshitaka MichihiroYutaka KishimotoTakashi Ohno
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1995 年 64 巻 2 号 p. 643-650

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The results of the temperature dependence of nuclear relaxation rate, 1/T1 measured for 23Na, 35Cl and 79Br in AgX and NaX with X being Cl and Br are interpreted in terms of the quadrupole relaxation due to lattice vibrations and defect motions. The data of 1/T1 in the low temperature region are compared with a model calculation based on an ionic model, in which the degree of covalency is estimated. The result is 24.5\an order of magnitude larger than the values in sodium halides. On the other hand, from an analysis of 1/T1 data in the high temperature region, the migration and formation energies of defects are evaluated and compared with the results of previous conductivity measurements. The obtained activation energies for migration are 0.27, eV in AgBr, 0.23, eV in AgCl and 0.60, eV in NaCl.
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© The Physical Society of Japan 1995
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