Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Magnetization and X-Ray Studies on (Fe1−xNix)3Ge and (Fe1−xNix)3.4Ge
Kazuo KanematsuHiroshi Takahashi
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1984 年 53 巻 7 号 p. 2376-2380

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By X-ray studies, three phases, hcp, bcc and fcc are found in x≤0.05, 0.15≤x≤0.5 and 0.6≤x for (Fe1−xNix)3Ge and in x<0.01, 0.1≤x≤0.5 and 0.6≤x for (Fe1−xNix)3.4Ge. The magnetization studies show a discrepancy about the boundary compositions, especially between the hcp and bcc phases. The alloys of both systems in 0.8≥x are ferromagnetic. In the hcp alloys of (Fe, Ni)3Ge, the magnetization decreases remarkably with the substitution of nickel, while the Curie temperature stays at about 600 K. In the bcc alloys, the magnetic moment per metal and the Curie temperature lower from 1.6 μB, 770 K of x=0.15 to 1.2 μB, 570 K of x=0.5 for (Fe, Ni)3Ge, and from 1.85 μB, 820 K of x=0.1 to 1.48 μB, 640 K of x=0.4 for (Fe, Ni)3.4Ge respectively. The Curie temperature of both fcc alloys lowers from 420 K of x=0.6 to 320 K of x=0.8.
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