高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
特集:高圧力が拓く流体の分子描像
X線・中性子を利用した高温高圧下における電解質溶液の構造解析
吉田 亨次山口 敏男
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ジャーナル フリー

2018 年 28 巻 2 号 p. 72-80

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In this article, recent researches on ionic hydration in subcritical and supercritical water with neutron diffraction (ND) and X-ray absorption spectroscopy (XAS) were introduced. ND with an isotopic substitution technique is one of the powerful methods to reveal the hydration structure of ions in electrolyte solutions. XAS can also observe the hydration structure of ions and ion-pair formation at a lower concentration of the ions. The fundamental information on ionic hydration is important to understand the underlying mechanism of formation of metal oxide nanoparticles from electrolyte solutions in subcritical and supercritical water, which is expected as a new fabrication technique of nanoparticles in the engineering field.
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© 2018 日本高圧力学会
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