抄録
The spreading of a non-functional polymeric liquid film on a solid surface was studied at molecular resolution by using Monte Carlo simulations. As model molecules, a linear chain polymer perfluoropolyether Z was employed and simplified as a set of beads connected by springs. Movement of the beads was made in an off-lattice three-dimensional space following the law of energy minimization. By introducing a method for identifying film surface from molecular number density, spreading profile of the polymeric film was obtained, showing similarity to the experimental measured result.
