材料
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
論文
ミストCVDで成膜した炭素ドープイットリウムチタナート(YTiOx)薄膜の構造解析および電気特性
吾妻 正道, 池田 守, 宮本 翼, 浅井 雅史, 鐘ケ江 一孝, 西中 浩之
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2026 年 75 巻 3 号 p. 239-243

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In this study, carbon-doped Y2Ti2O7 and TiO2 22% - 1/2 (Y2O3) 78% (TiO2 22%-YTO) thin films were fabricated using mist CVD method under atmospheric pressure, and their structural analysis and electrical characteristics were evaluated. These films were formed using a low-temperature process with maximum heat treatment at 430°C and exhibited memory switching properties based on metal-insulator transition (MIT). The fabricated devices showed an initial low-resistance metallic state (Born-on characteristic) and demonstrated non-polar switching behavior, transitioning to a high-resistance insulating state when a voltage of approximately 0.7 V was applied. Furthermore, TiO2 22%-YTO maintained similar switching performance at 200°C as at room temperature, confirming operation over a wide temperature range. SIMS analysis confirmed approximately 0.4% carbon doping in the films, which is believed to create impurity levels that enable metal-insulator transitions in Mott-Hubbard insulators. The material system developed in this research is promising for applications in correlated electron random access memory (CeRAM) that operates at low voltages over a broad temperature range.

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© 2026 日本材料学会

この記事はクリエイティブ・コモンズ [表示 - 非営利 - 改変禁止 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
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